How to Send Free SMS text messages in Nigeria via SMS text Website
How to Send Free SMS text messages in Nigeria via SMS Website
If you live in Nigeria, and you do not want to use your phone to send SMS, then you have a second option of sending Free SMS with your computer and an internet connection.
For those of you who want to spend some money or for those of you who do not like free sms, you can use paid sms at http://www.customizesms.com/ to send your sms to your family and friends.
Now, Here comes You Great Free SMS Text Message Tool
For those of you who like free stuffs, here is the big deal when it comes to sending fress SMS via the internet.
If you feel like sending or rather want to send fress sms via your internet conncetion in Nigeria, you can use MJOY http://www.mjoy.com/
With MJOY, you can send fress text messages from the comfort of your laptop connected to the internet.
Sending Free SMS with MJoy is very easy. All you neet is to visit http://www.mjoy.com/ and register for an account. After which you do mobile verification. Then just follow the instructions and you will be sending your first Free SMS Text message any moment from now
Enjoy your free sms text message while it lasts. Notting good or free last forever.
Tips and How to Get Scholarship in Nigeria, Ghana
How to Get Scholarships - How to Get Scholarships in Nigeria, Ghana, Togo, ...
Scholarships are tricky things. Everyone wants one. Few people get them. Apparently, there are millions out there that go unused on an annual basis. Because scholarships differ from loans in that they are free money, they are coveted beautiful things. They are also brilliant resume boosters and look fantastic on any resume.
Now, there are so many types of scholarships, it helps to be abreast of the types, time ranges, amounts, and places to find them. Some high schools give away scholarships prior to attending college. Some scholarships are merit based, others need based, others interest based, other cultural based. The list goes on.
The best way to begin seeking scholarships is to do your research. Every college and university will have a dowry with various scholarships. Usually they will be listed on the school's website; however, you can always inquire as to their prevalence. When you learn about them, you can find out how much, many, and reasons behind them. Essentially, scholarships don't usually just get handed to you (although some lucky people do find this fortuitous world). You must do your research.
Here are some types of scholarships.
Website: www.escholar.info
Books:
A mother was at home, and there was a knock at the door. She opened the door and was surprised to see a person standing there with a bouquet of flowers. It wasn’t a holiday, birthday, or anniversary. The flowers were a total surprise!
Scholarships are tricky things. Everyone wants one. Few people get them. Apparently, there are millions out there that go unused on an annual basis. Because scholarships differ from loans in that they are free money, they are coveted beautiful things. They are also brilliant resume boosters and look fantastic on any resume.
Now, there are so many types of scholarships, it helps to be abreast of the types, time ranges, amounts, and places to find them. Some high schools give away scholarships prior to attending college. Some scholarships are merit based, others need based, others interest based, other cultural based. The list goes on.
The best way to begin seeking scholarships is to do your research. Every college and university will have a dowry with various scholarships. Usually they will be listed on the school's website; however, you can always inquire as to their prevalence. When you learn about them, you can find out how much, many, and reasons behind them. Essentially, scholarships don't usually just get handed to you (although some lucky people do find this fortuitous world). You must do your research.
Here are some types of scholarships.
- Merit Scholarships - Scholarships typically revolve around this type of award. People who excel in academics are awarded a scholarship on the basis of their overall academic achievement. This may come in the form of top GPA, excellent SAT scores, and so on. These are highly competitive and may come in various forms.
- Need-Based Scholarships - This type of scholarship is given purely on financial means. They are designed to fund the less-fortunate students in their academic pursuits. Scholarship committees look at various reasons for this hardship: Parents' income, number of siblings in school simultaneously, expenses, cost of living, etc.
- Athletic Scholarships - Scholarships are popularly given to star athletes by universities to recruit them for the athletic teams. Many athletes complete their education free of charge, but also pay the price of overworked team sports. Usually full-scholarship athletes are recruited by "scouts" while in high school. You don't usually pursue this type of scholarship; it is given to you.
- School-Based Individual Scholarships - Every school offers specific scholarships relevant to specifics from the university: donors, individual name scholarships, personal scholarships, and so on. Sometimes you have to apply directly to the scholarship, and other times, just by being accepted, you are placed in the bowl for possible scholarship awards.
- Full/Partial Scholarship - Many people look at scholarships as a whole and think that they sometimes cover everything. If you are lucky enough to receive a full scholarship, then yes, they cover living, books, and tuition. However, many scholarships are partial, meaning they may cover simply living, simply books, or part of the tuition. If you are awarded any type of scholarship, take it and run! They are prized, wonderful gifts, and you should feel honored to receive one.
Website: www.escholar.info
Books:
- How To Go To College Almost For Free by Ben Kaplan
Winning Hearts Leads to Winning College Scholarships
A mother was at home, and there was a knock at the door. She opened the door and was surprised to see a person standing there with a bouquet of flowers. It wasn’t a holiday, birthday, or anniversary. The flowers were a total surprise!
They turned a rather ordinary day into an exceptional one to be remembered for weeks to come.
Little remembrances are cherished. And, the person who sends them is not forgotten. We all like to be remembered in unusual and caring ways.
The teachers and staffs of high schools aren’t any different and yet, it does not happen very often for them. Kind words are good, but a thoughtful note is better, and a small gift is best.
A teacher remarked that she once had a student who had many physical issues. It created some unusual classroom problems in her chemistry class. The mother of that student knew this
and constantly thanked the teacher with complimentary notes and small gifts throughout the school year not just on holidays. It made the teacher feel appreciated, needed, and
respected.
A typical high school has administrators, teachers, and a support staff. Who will be affecting your student? Who will your student have for classroom teachers in the coming year?
Find out who they are. You will want to know the
receptionist at the main desk. Don’t forget the secretary in the guidance office. Who cooks the lunches, sweeps the floors, and empties the wastebaskets? Bus drivers often have a particularly difficult situation. Also remember the principal and vice-principal. Many times all of these people are only remembered when something negative happens. Letting them know that you recognize and appreciate the jobs they’re
performing, for the benefit of your child, will make it easier for your student.
Favors and kindnesses are always returned. Find out when those birthdays and anniversaries happen and remember them with a card, note or even cookies. And, in those few short years, when college scholarship time rolls around, people
will be happy to write glowing testimonials for your student.
Remember this: everything in life is a decision, make the right ones today for your college scholarship success.
Labels:
Tips
Nigeria Court Orders Vice President to Assume Executive Powers
A Nigeria federal court has ordered Vice President Goodluck Jonathan to take over presidential duties in the absence of President Umaru Yar'Adua. The court announcement comes a day after thousands of protesters marched through the streets of the capital city demanding the vice president assume executive powers.
The ruling was in response to one of at least four separate suits filed by groups and individuals in Nigeria seeking to temporarily transfer executive powers to Vice President Goodluck Jonathan, and provide the country with interim leadership.
The Nigerian constitution requires the president to write to the National Assembly vesting the vice president with the powers to act as president. President Yar'Adua did not transfer powers to his deputy before traveling to Saudi Arabia for medical treatment in November.
The court accepted the argument that his continued absence and the power vacuum it has created could be a source of instability in Africa's most populous nation and ordered the vice president to immediately assume the position of acting president for the period of Mr.Yar'Adua's incapacitation.
A Nigerian lawyer based in Abuja, Maxi Okwu, welcomed the court decision.
"That is a welcomed relief. At least let somebody be in charge, somebody we can hold accountable. For the past 50 days this nation has been without a leader. You cannot rule a country by proxy. Now Goodluck has enough reasons to take over without appearing to disloyal. He should step in immediately," said Okwu.
The government is facing growing pressure over a perceived lack of leadership, given the continued absence of President Yar'Adua and persistent rumors over his state of health.
The Nigeria Bar Association, a prominent human-rights lawyer and two former lawmakers have all filed a legal challenge against the government, accusing Mr.Yar'Adua of breaching the constitution by staying in power.
Sourc: Voa News
The ruling was in response to one of at least four separate suits filed by groups and individuals in Nigeria seeking to temporarily transfer executive powers to Vice President Goodluck Jonathan, and provide the country with interim leadership.
The Nigerian constitution requires the president to write to the National Assembly vesting the vice president with the powers to act as president. President Yar'Adua did not transfer powers to his deputy before traveling to Saudi Arabia for medical treatment in November.
The court accepted the argument that his continued absence and the power vacuum it has created could be a source of instability in Africa's most populous nation and ordered the vice president to immediately assume the position of acting president for the period of Mr.Yar'Adua's incapacitation.
A Nigerian lawyer based in Abuja, Maxi Okwu, welcomed the court decision.
"That is a welcomed relief. At least let somebody be in charge, somebody we can hold accountable. For the past 50 days this nation has been without a leader. You cannot rule a country by proxy. Now Goodluck has enough reasons to take over without appearing to disloyal. He should step in immediately," said Okwu.
The government is facing growing pressure over a perceived lack of leadership, given the continued absence of President Yar'Adua and persistent rumors over his state of health.
The Nigeria Bar Association, a prominent human-rights lawyer and two former lawmakers have all filed a legal challenge against the government, accusing Mr.Yar'Adua of breaching the constitution by staying in power.
Sourc: Voa News
Labels:
News
Update on Haiti's Worst Earthquake
Untold Numbers Still Trapped in Rubble of Worst Quake in Haitian History
As untold numbers lay dead and or buried in the rubble of Haiti's worst earthquake ever, the impoverished nation is calling on the world to help.It was a nation already vulnerable, the poorest in the Western hemisphere, with a history of lax construction. The International Red Cross says the 7.0 earthquake in Haiti leaves close to a third of the population in need of emergency aid. Thousands are feared dead.
"What I know is that Port-au-Prince has been destroyed beginning with the palace, which is a very solid building. If the place itself is hit that hard imagine what happens to the flimsy abodes hanging by the flanks, the sides of hills surrounding Port-au-Prince. It's going to be a major catastrophe," said Haiti's ambassador to the United States, Raymond Joseph.
Joseph is calling for up to quadruple the amount of U.S. aid to his country, which now stands at about $300 million. He calls on the international community to help as well.
"Because the way it is, Port-au-Prince has to be rebuilt," he added. "And I think a lot of the shanty towns that were crushed should not be rebuilt in Port-Au-Prince. Decentralized."
On Wednesday, U.S. President Barack Obama promised a full-scale humanitarian effort.
"I have directed my administration to respond with a swift, coordinated and aggressive effort to save lives," he said.
The United Nations said Wednesday that more than 100 people are missing from its wrecked headquarters.
"The U.N. Headquarters at the Christopher Hotel collapsed in the quake," said Mr. Ban. "Many people are still trapped inside."
Meantime, aid from around the world is bound for Haiti on its way from a range of countries including Iceland, China and Israel.
"We are heading to Haiti together with the first delegation of the Army's Home Front Command so we can examine how Israel can help in this terrible tragedy," said Danny Saaban of the Israeli Foreign Ministry.
People have sent their donations to various relief organizations and their prayers, including the Pope.
"I assure my spiritual closeness to those who have lost their homes, and to all the people who are suffering in various ways for this calamity," said Pope Benedict.
The United Nations reports that the main airport in Haiti's capital is operational and open to relief flights in the coming days.
Scientists with the U.S. Geological Survey say the earthquake struck about 10 kilometers from Port-au-Prince, Tuesday afternoon. The initial quake registered at magnitude 7 on the Richter Scale and was followed by several other shocks, including one that measured 5.9.
Julie Dutton is a geophysicist with the U.S. Geological Survey.
"It is a pretty significant earthquake," Dutton said. "Given the size and location, we are anticipating some significant damage from the region."
Witnesses said a hospital in the capital collapsed, a luxury hotel in Petionville had sustained major damage and many other buildings were destroyed. The United Nations said there was serious damage to the headquarters of its mission in Haiti, and a large number of staff were unaccounted for.
Additional information from the island has been slow in coming, as telephone service from abroad has been disrupted.
Geophysicist Julie Dutton says she expects the damage to be severe, in part because many buildings are not designed to withstand earthquakes.
"This is actually the largest earthquake we have seen in the last 200 years in this region," she noted. "There has not been a earthquake of Magnitude 6 range since the 1970s."
In Washington, President Barack Obama said the country stood ready to assist the people of Haiti and said his thoughts and prayers go out to those affected by the quake.
Secretary of State Hillary Clinton said officials were beginning to assess the disaster and deploy emergency aid to Haiti.
"The United States is offering our full assistance to Haiti and others in the region. We will be offering both civilian and military disaster relief and humanitarian assistance," Clinton said.
Officials with the U.S. Agency for International Development said they were preparing to send a response team that includes 72 people, six search and rescue dogs and 48 tons of rescue equipment.
The quake was also felt in Dominican Republic, which shares the island of Hispaniola with Haiti. Residents on the nearby island of Cuba also said they felt the quake, but no damage was reported.
Source: Voice of America
Labels:
News. Earthquake News
What is Oinkernet - Oinkernet is a new website that features guinea pigs
What is Oinkernet -
Oinkernet is taking a buzz in the world wide web. Oinkernet is a a new website that features guinea pigs. This site is automatically updated every two minutes
Oinkernet is taking a buzz in the world wide web. Oinkernet is a a new website that features guinea pigs. This site is automatically updated every two minutes
Under The Milky Way
Under The Milky Way Details
- Original Release Date: September 28, 1999
- Label: Buddha Records
- Copyright: (P) 1999 Buddha Records
- Total Length: 1:15:2
Mark McGwire and His Steroids Confession
Mark McGwire Makes a Big Confession on use of Steroids
Mark McGwire has made a great confession today.
Mark McGwire, Retired baseball admitted that he has used steroids during his period of playing baseball, , including when he broke the sport's home run record in 1998.
Mark McGwire said he had used steroids occasionally for about 10 years now and apologised.
"I used steroids during my playing career and I apologise," Mark McGwire said in a statement published on the Major League Baseball (MLB) website.
Mark McGwire said he remembered trying steroids very briefly in the 1989-1990 offseason when he was injured and1993.
Mark McGwire admitted using steroids occasion throughout the 90s, including during the 1998 season and wished he never touched steroids."
Mark McGwire added: "It was foolish and it was a mistake. I truly apologise. Looking back, I wish I had never played during the steroid era."
Mark McGwire has made a great confession today.
Mark McGwire, Retired baseball admitted that he has used steroids during his period of playing baseball, , including when he broke the sport's home run record in 1998.
Mark McGwire said he had used steroids occasionally for about 10 years now and apologised.
"I used steroids during my playing career and I apologise," Mark McGwire said in a statement published on the Major League Baseball (MLB) website.
Mark McGwire said he remembered trying steroids very briefly in the 1989-1990 offseason when he was injured and1993.
Mark McGwire admitted using steroids occasion throughout the 90s, including during the 1998 season and wished he never touched steroids."
Mark McGwire added: "It was foolish and it was a mistake. I truly apologise. Looking back, I wish I had never played during the steroid era."
Drop a Comment for Mark McGwire and His Steroids Confession
Labels:
Mark McGwire
Mark McGwire
According to Wikipedia, Mark McGwire (born October 1, 1963) is a former Major League Baseball player who played his major league career with the Oakland Athletics and the St. Louis Cardinals.[1] He is replacing Hal McRae as the hitting coach for the St. Louis Cardinals for 2010.[2]
For his career, McGwire averaged a home run once every 10.61 at bats, the lowest at bats per home run ratio in baseball history (Ryan Howard is second at 11.32 and Babe Ruth is third at 11.80).[3] In 1987, he broke the single-season home run record for rookies, with 49. In 1998, McGwire and Sammy Sosa achieved national fame for their home run-hitting prowess in pursuit of Roger Maris' single season home run record; McGwire would break the record and hit 70 home runs that year.
For his career, McGwire averaged a home run once every 10.61 at bats, the lowest at bats per home run ratio in baseball history (Ryan Howard is second at 11.32 and Babe Ruth is third at 11.80).[3] In 1987, he broke the single-season home run record for rookies, with 49. In 1998, McGwire and Sammy Sosa achieved national fame for their home run-hitting prowess in pursuit of Roger Maris' single season home run record; McGwire would break the record and hit 70 home runs that year.
Portable Acetylene Lamps and Plants
PORTABLE ACETYLENE LAMPS AND PLANT
In several important respects portable acetylene apparatus may be divided into two classes from a practical point of view. There is the portable table or stand lamp intended for use in an occupied room, and there is the hand or supported lamp intended for the illumination of vehicles or open-air spaces. Economy apart, no difficulty arises from imperfect combustion or escape of unburnt gas from an outdoor lamp, but in a room the presence of unburnt acetylene must always be offensive even if it is not dangerous; while the combustion products of the impurities—and in a portable generator acetylene cannot be chemically purified—are highly objectionable. It is simply a matter of good design to render any form of portable apparatus safe against explosion (employment of proper carbide being assumed), for one or more vent-pipes can always be inserted in the proper places; but from an indoor lamp those vent-pipes cannot be made to discharge into a place of safety, while, as stated before, a generator in which the vent-pipes come into action with any frequency is but an extravagant piece of apparatus for the decomposition of so costly a material as calcium carbide. Looked at from one aspect the holder of a fixed apparatus is merely an economical substitute for the wasteful vent- pipe, because it is a place in which acetylene can be held in reserve whenever the make exceeds the consumption in speed. It is perhaps possible to conceive of a large table acetylene lamp fitted with a water- sealed rising holder; but for vehicular purposes the displacement holder is practically the only one available, and in small apparatus it becomes too minute in size to be of much service as a store for the gas produced by after-generation. Other forms of holder have been suggested by inventors, such as a collapsible bag of india-rubber or the like; but rubber is too porous, weak, and perishable a material to be altogether suitable. If it is possible, by bringing carbide and water into mutual contact in predetermined quantities, to produce gas at a uniform rate, and at one which corresponds with the requirements of the burner, in a small apparatus—and experience has shown it to be possible within moderately satisfactory limits—it is manifest that the holder is only needed to take up the gas of after-generation; and in Chapters II. and III. it was pointed out that after-generation only occurs when water is brought into contact with an excess of carbide. If, then, the opposite system of construction is adopted, and carbide is fed into water mechanically, no after-generation can take place; and provided the make of gas can be controlled in a small carbide-feed generator as accurately as is possible in a small water-to-carbide generator, the carbide-feed principle will exhibit even greater advantages in portable apparatus than it does in plant of domestic size. Naturally almost every variety of carbide-feeding gear, especially when small, requires or prefers granulated (or granulated and "treated") carbide; and granulated carbide must inevitably be considerably more expensive per unit of light evolved than the large material, but probably in the application to which the average portable acetylene apparatus is likely to be put, strict economy is not of first consequence. In portable acetylene generators of the carbide-feed type, the supply is generally governed by the movements of a mushroom-headed or conical valve at the mouth of a conical carbide vessel; such movements occurring in sympathy with the alterations in level of the water in the decomposing chamber, which is essentially a small displacement holder also, or being produced by the contraction of a flexible chamber through which the gas passes on its way to the burner. So far as it is safe to speak definitely on a matter of this kind, the carbide-feed device appears to work satisfactorily in a stationary (e.g., table) lamp; but it is highly questionable whether it could be applied to a vehicular apparatus exposed to any sensible amount of vibration. The device is satisfactory on the table of an occupied room so far, be it understood, as any small portable generators can be: it has no holder, but since no after-generation occurs, no holder is needed; still the combustion products contaminate the room with all the sulphur and phosphorus of the crude acetylene.
For vehicular lamps, and probably for hand lanterns, the water-to-carbide system has practically no alternative (among actual generators), and safety and convenience have to be gained at the expense of the carbide. In such apparatus the supply of water is usually controlled ultimately by pressure, though a hand-operated needle-valve is frequently put on the water tube. The water actually reaches the carbide either by dropping from a jet, by passing along, upwards or downwards, a "wick" such as is used in oil-lamps, or by percolating through a mass of porous material like felt. The carbide is held in a chamber closed except at the gas exit to the burner and at the inlet from the water reservoir: so that if gas is produced more rapidly than the burner takes it, more water is prevented from entering, or the water already present is driven backwards out of the decomposing chamber into some adjoining receptacle. It is impossible to describe in detail all the lamps which have been constructed or proposed for vehicular use; and therefore the subject must be approached in general terms, discussing simply the principles involved in the design of a safe portable generator.
In all portable apparatus, and indeed in generators of larger dimensions, the decomposing chamber must be so constructed that it can never, even by wrong manipulation, be sealed hermetically against the atmosphere. If there is a cock on the water inlet tube which is capable of being completely shut, there must be no cock between the decomposing chamber and the burner. If there is a cock between the carbide vessel and the burner, the water inlet tube must only be closed by the water, being water-sealed, in fact, so that if pressure rises among the carbide the surplus gas may blow the seal or bubble through the water in the reservoir. If the water-supply is mainly controlled by a needle-valve, it is useful to connect the burner with the carbide vessel through a short length of rubber tube; and if this plan is adopted, a cock can, if desired, be put close to the burner. The rubber should not be allowed to form a bend hanging down, or water vapour, &c., may condense and extinguish the flame. In any case there should be a steady fall from the burner to the decomposing chamber, or to some separate catch-pit for the products of condensation. Much of the success attainable with small generators will depend on the water used. If it is contaminated with undissolved matter, the dirt will eventually block the fine orifices, especially the needle-valve, or will choke the pores of the wick or the felt pad. If the water contains an appreciable amount of "temporary hardness," and if it becomes heated much in the lamp, fur will be deposited sooner or later, and will obviously give trouble. Where the water reservoir is at the upper part of the lamp, and the liquid is exposed to the heat of the flame, fur will appear quickly if the water is hard. Considerable benefit would accrue to the user of a portable lamp by the employment of rain water filtered, if necessary, through fabric or paper. The danger of freezing in very severe weather may be prevented by the use of calcium chloride, or preferably, perhaps, methylated spirit in the water (cf. Chapter III., p. 92). The disfavour with which cycle and motor acetylene lamps are frequently regarded by nocturnal travellers, other than the users thereof, is due to thoughtless design in the optical part of such lamps, and is no argument against the employment of acetylene. By proper shading or deflection of the rays, the eyes of human beings and horses can be sufficiently protected from the glare, and the whole of the illumination concentrated more perfectly on the road surface and the lower part of approaching objects—a beam of light never reaching a height of 5 feet above the ground is all that is needed to satisfy all parties.
As the size of the generator rises, conditions naturally become more suited to the construction of a satisfactory apparatus; until generators intended to supply light to the whole of (say) a railway carriage, or the head and cab lamps of a locomotive, or for the outside and inside lighting of an omnibus are essentially generators of domestic dimensions somewhat altered in internal construction to withstand vibration and agitation. As a rule there is plenty of space at the side of a locomotive to carry a generator fitted with a displacement holder of sufficient size, which is made tall rather than wide, to prevent the water moving about more than necessary. From the boiler, too, steam can be supplied to a coil to keep the liquid from freezing in severe weather. Such apparatus need not be described at length, for they can be, and are, made on lines resembling those of domestic generators, though more compactly, and having always a governor to give a constant pressure. For carriage lighting any ordinary type of generator, preferably, perhaps, fitted with a displacement holder, can be erected either in each corridor carriage, or in a brake van at the end of the train. Purifiers may be added, if desired, to save the burners from corrosion; but the consumption of unpurified gas will seldom be attended by hygienic disadvantages, because the burners will be contained in closed lamps, ventilating into the outside air. The generator, also, may conveniently be so constructed that it is fed with carbide from above the roof, and emptied of lime sludge from below the floor of the vehicle. It can hardly be said that the use of acetylene generated on board adds a sensible risk in case of collision. In the event of a subsequent fire, the gas in the generator would burn, but not explode; but in view of the greater illuminating power per unit volume of carbide than per equal volume of compressed oil- gas, a portable acetylene generator should be somewhat less objectionable than broken cylinders of oil-gas if a fire should follow a railway accident of the usual kind. More particularly by the use of "cartridges" of carbide, a railway carriage generator can be constructed of sufficient capacity to afford light for a long journey, or even a double journey, so that attention would be only required (in the ordinary way) at one end of the line.
Passing on from the generators used for the lighting of vehicles and for portable lamps for indoor lighting to the considerably larger portable generators now constructed for the supply of acetylene for welding purposes and for "flare" lamps, it will be evident that they may embody most or all of the points which are essential to the proper working of a fixed generator for the supply of a small establishment. The holder will generally be of the displacement type, but some of these larger portable generators are equipped with a rising holder. The generators are, naturally, automatic in action, but may be either of the water-to-carbide or carbide-to-water type—the latter being preferable in the larger sizes intended for use with the oxy-acetylene blow-pipe for welding, &c., for which use a relatively large though intermittent supply of acetylene is called for. The apparatus is either carried by means of handles or poles attached to it, or is mounted on a wheelbarrow or truck for convenience of transport to the place where it is to be used. The so called "flare" lamps, which are high power burners mounted, with or without a reflector, above a portable generator, are extremely useful for lighting open spaces where work has to be carried on temporarily after nightfall, and are rapidly displacing oil-flares of the Lucigen type for such purposes.
The use of "cartridges" of calcium carbide has already been briefly referred to in Chapters II. and III. These cartridges are usually either receptacles of thin sheet-metal, say tin plate, or packages of carbide wrapped up in grease proof paper or the like. If of metal, they may have a lid which is detached or perforated before they are put into the generator, or the generator (when automatic and of domestic size) may be so arranged that a cartridge is punctured in one or more places whenever more gas is required. If wrapped in paper, the cartridges may be dropped into water by an automatic generator at the proper times, the liquid then loosening the gum and so gaining access to the interior; or one spot may be covered by a drape of porous material (felt) only, through which the water penetrates slowly. The substance inside the cartridge may be ordinary, granulated, or "treated" carbide. Cartridges or "sticks" of carbide are also made without wrappings, either by moistening powdered carbide with oil and compressing the whole into moulds, or by compressing dry carbide dust and immersing the sticks in oil or molten grease. The former process is said to cause the carbide to take up too much oil, so that sticks made by the second method are reputed preferable. All these cartridges have the advantage over common carbide of being more permanent in damp air, of being symmetrical in shape, of decomposing at a known speed, and of liberating acetylene in known quantity; but evidently they are more expensive, owing to the cost of preparing them, &c. They may be made more cheaply from the dust produced in the braking of carbide, but in that case the yield of gas will be relatively low.
It is manifest that, where space is to spare, purifiers containing the materials mentioned in Chapter V. can be added to any portable acetylene apparatus, provided also that the extra weight is not prohibitive. Cycle lamps and motor lamps must burn an unpurified gas unpurified from phosphorus and sulphur; but it is always good and advisable to filter the acetylene from dust by a plug of cotton wool or the like, in order to keep the burners as clear as may be. A burner with a screwed needle for cleaning is always advantageous. Formerly the burners used on portable acetylene lamps were usually of the single jet or rat-tail, or the union jet or fish tail type, and exhibited in an intensified form, on account of their small orifices, all the faults of these types of burners for the consumption of acetylene (see Chapter VIII.). Now, however, there are numerous special burners adapted for use in acetylene cycle and motor lamps, &c., and many of these are of the impinging jet type, and some have steatite heads to prevent distortion by the heat. One such cycle- lamp burner, as sold in England by L. Wiener, of Fore Street, London, is shown in Fig. 21. A burner constructed like the "Kona" (Chapter VIII.) is made in small sizes (6, 8 and 10 litres per hour) for use in vehicular lamps, under the name of the "Konette," by Falk, Stadelmann and Co., Ltd., of London, who also make a number of other small impinging jet burners. A single jet injector burner on the "Phôs" principle is made in small sizes by the Phôs Co., of London, specially for use in lamps on vehicles.
[Illustration: FIG. 21.—CYCLE-LAMP BURNER NO. 96042A.]
Nevertheless, although satisfactory medium-sized vehicular lamps for the generation of acetylene have been constructed, the best way of using acetylene for all such employments as these is to carry it ready made in a state of compression. For railway purposes, where an oil-gas plant is in existence, and where it is merely desired to obtain a somewhat brighter light, the oil-gas may be enriched with 20 per cent. of acetylene, and the mixed gas pumped into the same cylinders to a pressure of 10 atmospheres, as mentioned in Chapter XI.; the only alteration necessary being the substitution of suitable small burners for the common oil-gas jets. As far as the plant is concerned, all that is required is a good acetylene generator, purifier, and holder from which the acetylene can be drawn or forced through a meter into a larger storage holder, the meter being connected by gearing with another meter on the pipe leading from the oil-gas holder to the common holder, so that the necessary proportions of the two gases shall be introduced into the common holder simultaneously. From this final holder the enriched gas will be pumped into the cylinders or into a storage cylinder, by means of a thoroughly cooled pump, so that the heat set free by the compression may be safely dissipated.
Whenever still better light is required in railway carriages, as also for the illumination of large, constantly used vehicles, such as omnibuses, the acetone process (cf. Chapter XI.) exhibits notable advantages. The light so obtained is the light of neat acetylene, but the gas is acetylene having an upper limit of explosibility much lower than usual because of the vapour of acetone in it. In all other respects the presence of the acetone will be unnoticeable, for it is a fairly pure organic chemical body, which burns in the flame completely to carbon dioxide and water, exactly as acetylene itself does. If the acetylene is merely compressed into porous matter without acetone, the gas burnt is acetylene simply; but per unit of volume or weight the cylinders will not be capable of developing so much light.
In the United States, at least one railway system (The Great Northern) has a number of its passenger coaches lighted by means of plain acetylene carried in a state of compression in cylinders without porous matter. The gas is generated, filtered from dust, and stored in an ordinary rising holder at a factory alongside the line; being drawn from this holder through a drier to extract moisture, and through a safety device, by a pump which, in three stages, compresses the acetylene into large storage reservoirs. The safety device consists of a heavy steel cylinder filled with some porous substance which, like the similar material of the acetone cylinders, prevents any danger of the acetylene contained in the water-sealed holder being implicated in an explosion starting backwards from the compression, by extinguishing any spark which might be produced there. The plant on the trains comprises a suitable number of cylinders, filled by contact with the large stores of gas to a pressure of 10 atmospheres, pipes of fusible metal communicating with the lamps, and ordinary half-foot acetylene burners. The cylinders are provided with fusible plugs, so that, in the event of a fire, they and the service- pipes would melt, allowing the gas to escape freely and burn in the air, instead of exploding or dissociating explosively within the cylinders should the latter be heated by any burning woodwork or the like. It is stated that this plan of using acetylene enables a quantity of gas to be carried under each coach which is sufficient for a run of from 53 to 70 hours' duration, or of over 3600 miles; that is to say, enables the train, in the conditions obtaining on the line in question, to make a complete "round trip" without exhaustion of its store of artificial light. The system has been in operation for some years, and appears to have been so carefully managed that no accident has arisen; but it is clear that elements of danger are present which are eliminated when the cylinders are loaded with porous matter and acetone. The use of a similar system of compressed acetylene train lighting in South America has been attended with a disastrous explosion, involving loss of life.
It may safely be said that the acetone system, or less conveniently perhaps the mere compression into porous matter, is the best to adopt for the table-lamp which is to be used in occupied rooms Small cylinders of such shapes as to form an elegant base for a table-lamp on more or less conventional lines would be easy to make. They would be perfectly safe to handle. If accidentally or wilfully upset, no harm would arise. By deliberate ill-treatment they might be burst, or the gas-pipe fractured below the reducing valve, so that gas would escape under pressure for a time; but short of this they would be as devoid of extra clangor in times of fire as the candle or the coal-gas burner. Moreover, they would only contaminate the air with carbon dioxide and water vapour, for the gas is purified before compression; and modern investigations have conclusively demonstrated that the ill effects produced in the air of an imperfectly ventilated room by the extravagant consumption of coal-gas depend on the accumulation of the combustion products of the sulphur in the gas rather than upon the carbon dioxide set free.
One particular application of the portable acetylene apparatus is of special interest. As calcium carbide evolves an inflammable gas when it merely comes into contact with water, it becomes possible to throw into the sea or river, by hand or by ejection from a mortar, a species of bomb or portable generator which is capable of emitting a powerful beam of light if only facilities are present for inflaming the acetylene generated; and it is quite easy so to arrange the interior of such apparatus that they can be kept ready for instant use for long periods of time without sensible deterioration, and that they can be recharged after employment. Three methods of firing the gas have been proposed. In one the shock or contact with the water brings a small electric battery into play which produces a spark between two terminals projecting across the burner orifice; in the second, a cap at the head of the generator contains a small quantity of metallic potassium, which decomposes water with such energy that the hydrogen liberated catches fire; and in the third a similar cap is filled with the necessary quantity of calcium phosphide, or the "carbophosphide of calcium" mentioned in Chapter XI., which yields a flame by the immediate ignition of the liquid phosphine produced on the attack of water. During the two or three seconds consumed in the production of the spark or pilot flame, the water is penetrating the main charge of calcium carbide in the interior of the apparatus, until the whole is ready to give a bright light for a time limited only by the capacity of the generator. It is obvious that such apparatus may be of much service at sea: they may be thrown overboard to illuminate separate lifebuoys in case of accident, or be attached to the lifebuoys they are required to illuminate, or be used as lifebuoys themselves if fitted with suitable chains or ropes; they may be shot ahead to illuminate a difficult channel, or to render an enemy visible in time of war. Several such apparatus have already been constructed and severely tested; they appear to give every satisfaction. They are, of course, so weighted that the burner floats vertically, while buoyancy is obtained partly by the gas evolved, and partly by a hollow portion of the structure containing air. Cartridges of carbide and caps yielding a self- inflammable gas can be carried on board ship, by means of which the torches or lifebuoys may be renewed after service in a few minutes' time.
It will be apparent from what has been said in past chapters that the construction of a satisfactory generator for portable purposes must be a problem of considerable complexity. A fixed acetylene installation tends to work the more smoothly, and the gas evolved therefrom to burn the more pleasantly, the more technically perfect the various subsidiary items of the plant are; that is to say, the more thoroughly the acetylene is purified, dried, and delivered at a strictly constant pressure to the burners and stoves. Moreover, the efficient behaviour of the generator itself will depend more upon the mechanical excellence and solidity of its construction than (with one or two exceptions) upon the precise system to which it belongs. And, lastly, the installation will, broadly speaking, work the better, the larger the holder is in proportion to the demands ever made upon it; while that holder will perform the whole duty of a gasholder more effectually if it belongs to the rising variety than if it is a displacement holder. All these requirements of a good acetylene apparatus have to be sacrificed to a greater or less extent in portable generators; and since the sacrifice becomes more serious as the generator is made smaller and lighter in weight, it may be said in general terms that the smaller a portable (or, indeed, other) acetylene apparatus is, the less complete or permanent satisfaction will it give its user. Again, small portable apparatus are only needed to develop intensities of light insignificant in comparison with those which may easily be won from acetylene on a larger scale; they are therefore fitted with smaller burners, and those burners are not merely small in terms of consumption and illuminating power, but not infrequently are very badly constructed, and are relatively deficient in economy or duty. Thus any comparisons which may be made on lines similar to those adopted in Chapter I., or between unit weights, volumes, or monetary equivalents of calcium carbide, paraffin, candles, and colza oil, become utterly incorrect if the carbide is only decomposed in a small portable generator fitted with an inefficient jet; first, because the latent illuminating power of the acetylene evolved is largely wasted; secondly, because any gas produced over and above that capable of instant combustion must be blown off from a vent-pipe; and thirdly, because the carbide itself tends to be imperfectly decomposed, either through a defect in the construction of the lamp, or through the brief and interrupted requirements of the consumer.
In several important respects portable acetylene apparatus may be divided into two classes from a practical point of view. There is the portable table or stand lamp intended for use in an occupied room, and there is the hand or supported lamp intended for the illumination of vehicles or open-air spaces. Economy apart, no difficulty arises from imperfect combustion or escape of unburnt gas from an outdoor lamp, but in a room the presence of unburnt acetylene must always be offensive even if it is not dangerous; while the combustion products of the impurities—and in a portable generator acetylene cannot be chemically purified—are highly objectionable. It is simply a matter of good design to render any form of portable apparatus safe against explosion (employment of proper carbide being assumed), for one or more vent-pipes can always be inserted in the proper places; but from an indoor lamp those vent-pipes cannot be made to discharge into a place of safety, while, as stated before, a generator in which the vent-pipes come into action with any frequency is but an extravagant piece of apparatus for the decomposition of so costly a material as calcium carbide. Looked at from one aspect the holder of a fixed apparatus is merely an economical substitute for the wasteful vent- pipe, because it is a place in which acetylene can be held in reserve whenever the make exceeds the consumption in speed. It is perhaps possible to conceive of a large table acetylene lamp fitted with a water- sealed rising holder; but for vehicular purposes the displacement holder is practically the only one available, and in small apparatus it becomes too minute in size to be of much service as a store for the gas produced by after-generation. Other forms of holder have been suggested by inventors, such as a collapsible bag of india-rubber or the like; but rubber is too porous, weak, and perishable a material to be altogether suitable. If it is possible, by bringing carbide and water into mutual contact in predetermined quantities, to produce gas at a uniform rate, and at one which corresponds with the requirements of the burner, in a small apparatus—and experience has shown it to be possible within moderately satisfactory limits—it is manifest that the holder is only needed to take up the gas of after-generation; and in Chapters II. and III. it was pointed out that after-generation only occurs when water is brought into contact with an excess of carbide. If, then, the opposite system of construction is adopted, and carbide is fed into water mechanically, no after-generation can take place; and provided the make of gas can be controlled in a small carbide-feed generator as accurately as is possible in a small water-to-carbide generator, the carbide-feed principle will exhibit even greater advantages in portable apparatus than it does in plant of domestic size. Naturally almost every variety of carbide-feeding gear, especially when small, requires or prefers granulated (or granulated and "treated") carbide; and granulated carbide must inevitably be considerably more expensive per unit of light evolved than the large material, but probably in the application to which the average portable acetylene apparatus is likely to be put, strict economy is not of first consequence. In portable acetylene generators of the carbide-feed type, the supply is generally governed by the movements of a mushroom-headed or conical valve at the mouth of a conical carbide vessel; such movements occurring in sympathy with the alterations in level of the water in the decomposing chamber, which is essentially a small displacement holder also, or being produced by the contraction of a flexible chamber through which the gas passes on its way to the burner. So far as it is safe to speak definitely on a matter of this kind, the carbide-feed device appears to work satisfactorily in a stationary (e.g., table) lamp; but it is highly questionable whether it could be applied to a vehicular apparatus exposed to any sensible amount of vibration. The device is satisfactory on the table of an occupied room so far, be it understood, as any small portable generators can be: it has no holder, but since no after-generation occurs, no holder is needed; still the combustion products contaminate the room with all the sulphur and phosphorus of the crude acetylene.
For vehicular lamps, and probably for hand lanterns, the water-to-carbide system has practically no alternative (among actual generators), and safety and convenience have to be gained at the expense of the carbide. In such apparatus the supply of water is usually controlled ultimately by pressure, though a hand-operated needle-valve is frequently put on the water tube. The water actually reaches the carbide either by dropping from a jet, by passing along, upwards or downwards, a "wick" such as is used in oil-lamps, or by percolating through a mass of porous material like felt. The carbide is held in a chamber closed except at the gas exit to the burner and at the inlet from the water reservoir: so that if gas is produced more rapidly than the burner takes it, more water is prevented from entering, or the water already present is driven backwards out of the decomposing chamber into some adjoining receptacle. It is impossible to describe in detail all the lamps which have been constructed or proposed for vehicular use; and therefore the subject must be approached in general terms, discussing simply the principles involved in the design of a safe portable generator.
In all portable apparatus, and indeed in generators of larger dimensions, the decomposing chamber must be so constructed that it can never, even by wrong manipulation, be sealed hermetically against the atmosphere. If there is a cock on the water inlet tube which is capable of being completely shut, there must be no cock between the decomposing chamber and the burner. If there is a cock between the carbide vessel and the burner, the water inlet tube must only be closed by the water, being water-sealed, in fact, so that if pressure rises among the carbide the surplus gas may blow the seal or bubble through the water in the reservoir. If the water-supply is mainly controlled by a needle-valve, it is useful to connect the burner with the carbide vessel through a short length of rubber tube; and if this plan is adopted, a cock can, if desired, be put close to the burner. The rubber should not be allowed to form a bend hanging down, or water vapour, &c., may condense and extinguish the flame. In any case there should be a steady fall from the burner to the decomposing chamber, or to some separate catch-pit for the products of condensation. Much of the success attainable with small generators will depend on the water used. If it is contaminated with undissolved matter, the dirt will eventually block the fine orifices, especially the needle-valve, or will choke the pores of the wick or the felt pad. If the water contains an appreciable amount of "temporary hardness," and if it becomes heated much in the lamp, fur will be deposited sooner or later, and will obviously give trouble. Where the water reservoir is at the upper part of the lamp, and the liquid is exposed to the heat of the flame, fur will appear quickly if the water is hard. Considerable benefit would accrue to the user of a portable lamp by the employment of rain water filtered, if necessary, through fabric or paper. The danger of freezing in very severe weather may be prevented by the use of calcium chloride, or preferably, perhaps, methylated spirit in the water (cf. Chapter III., p. 92). The disfavour with which cycle and motor acetylene lamps are frequently regarded by nocturnal travellers, other than the users thereof, is due to thoughtless design in the optical part of such lamps, and is no argument against the employment of acetylene. By proper shading or deflection of the rays, the eyes of human beings and horses can be sufficiently protected from the glare, and the whole of the illumination concentrated more perfectly on the road surface and the lower part of approaching objects—a beam of light never reaching a height of 5 feet above the ground is all that is needed to satisfy all parties.
As the size of the generator rises, conditions naturally become more suited to the construction of a satisfactory apparatus; until generators intended to supply light to the whole of (say) a railway carriage, or the head and cab lamps of a locomotive, or for the outside and inside lighting of an omnibus are essentially generators of domestic dimensions somewhat altered in internal construction to withstand vibration and agitation. As a rule there is plenty of space at the side of a locomotive to carry a generator fitted with a displacement holder of sufficient size, which is made tall rather than wide, to prevent the water moving about more than necessary. From the boiler, too, steam can be supplied to a coil to keep the liquid from freezing in severe weather. Such apparatus need not be described at length, for they can be, and are, made on lines resembling those of domestic generators, though more compactly, and having always a governor to give a constant pressure. For carriage lighting any ordinary type of generator, preferably, perhaps, fitted with a displacement holder, can be erected either in each corridor carriage, or in a brake van at the end of the train. Purifiers may be added, if desired, to save the burners from corrosion; but the consumption of unpurified gas will seldom be attended by hygienic disadvantages, because the burners will be contained in closed lamps, ventilating into the outside air. The generator, also, may conveniently be so constructed that it is fed with carbide from above the roof, and emptied of lime sludge from below the floor of the vehicle. It can hardly be said that the use of acetylene generated on board adds a sensible risk in case of collision. In the event of a subsequent fire, the gas in the generator would burn, but not explode; but in view of the greater illuminating power per unit volume of carbide than per equal volume of compressed oil- gas, a portable acetylene generator should be somewhat less objectionable than broken cylinders of oil-gas if a fire should follow a railway accident of the usual kind. More particularly by the use of "cartridges" of carbide, a railway carriage generator can be constructed of sufficient capacity to afford light for a long journey, or even a double journey, so that attention would be only required (in the ordinary way) at one end of the line.
Passing on from the generators used for the lighting of vehicles and for portable lamps for indoor lighting to the considerably larger portable generators now constructed for the supply of acetylene for welding purposes and for "flare" lamps, it will be evident that they may embody most or all of the points which are essential to the proper working of a fixed generator for the supply of a small establishment. The holder will generally be of the displacement type, but some of these larger portable generators are equipped with a rising holder. The generators are, naturally, automatic in action, but may be either of the water-to-carbide or carbide-to-water type—the latter being preferable in the larger sizes intended for use with the oxy-acetylene blow-pipe for welding, &c., for which use a relatively large though intermittent supply of acetylene is called for. The apparatus is either carried by means of handles or poles attached to it, or is mounted on a wheelbarrow or truck for convenience of transport to the place where it is to be used. The so called "flare" lamps, which are high power burners mounted, with or without a reflector, above a portable generator, are extremely useful for lighting open spaces where work has to be carried on temporarily after nightfall, and are rapidly displacing oil-flares of the Lucigen type for such purposes.
The use of "cartridges" of calcium carbide has already been briefly referred to in Chapters II. and III. These cartridges are usually either receptacles of thin sheet-metal, say tin plate, or packages of carbide wrapped up in grease proof paper or the like. If of metal, they may have a lid which is detached or perforated before they are put into the generator, or the generator (when automatic and of domestic size) may be so arranged that a cartridge is punctured in one or more places whenever more gas is required. If wrapped in paper, the cartridges may be dropped into water by an automatic generator at the proper times, the liquid then loosening the gum and so gaining access to the interior; or one spot may be covered by a drape of porous material (felt) only, through which the water penetrates slowly. The substance inside the cartridge may be ordinary, granulated, or "treated" carbide. Cartridges or "sticks" of carbide are also made without wrappings, either by moistening powdered carbide with oil and compressing the whole into moulds, or by compressing dry carbide dust and immersing the sticks in oil or molten grease. The former process is said to cause the carbide to take up too much oil, so that sticks made by the second method are reputed preferable. All these cartridges have the advantage over common carbide of being more permanent in damp air, of being symmetrical in shape, of decomposing at a known speed, and of liberating acetylene in known quantity; but evidently they are more expensive, owing to the cost of preparing them, &c. They may be made more cheaply from the dust produced in the braking of carbide, but in that case the yield of gas will be relatively low.
It is manifest that, where space is to spare, purifiers containing the materials mentioned in Chapter V. can be added to any portable acetylene apparatus, provided also that the extra weight is not prohibitive. Cycle lamps and motor lamps must burn an unpurified gas unpurified from phosphorus and sulphur; but it is always good and advisable to filter the acetylene from dust by a plug of cotton wool or the like, in order to keep the burners as clear as may be. A burner with a screwed needle for cleaning is always advantageous. Formerly the burners used on portable acetylene lamps were usually of the single jet or rat-tail, or the union jet or fish tail type, and exhibited in an intensified form, on account of their small orifices, all the faults of these types of burners for the consumption of acetylene (see Chapter VIII.). Now, however, there are numerous special burners adapted for use in acetylene cycle and motor lamps, &c., and many of these are of the impinging jet type, and some have steatite heads to prevent distortion by the heat. One such cycle- lamp burner, as sold in England by L. Wiener, of Fore Street, London, is shown in Fig. 21. A burner constructed like the "Kona" (Chapter VIII.) is made in small sizes (6, 8 and 10 litres per hour) for use in vehicular lamps, under the name of the "Konette," by Falk, Stadelmann and Co., Ltd., of London, who also make a number of other small impinging jet burners. A single jet injector burner on the "Phôs" principle is made in small sizes by the Phôs Co., of London, specially for use in lamps on vehicles.
[Illustration: FIG. 21.—CYCLE-LAMP BURNER NO. 96042A.]
Nevertheless, although satisfactory medium-sized vehicular lamps for the generation of acetylene have been constructed, the best way of using acetylene for all such employments as these is to carry it ready made in a state of compression. For railway purposes, where an oil-gas plant is in existence, and where it is merely desired to obtain a somewhat brighter light, the oil-gas may be enriched with 20 per cent. of acetylene, and the mixed gas pumped into the same cylinders to a pressure of 10 atmospheres, as mentioned in Chapter XI.; the only alteration necessary being the substitution of suitable small burners for the common oil-gas jets. As far as the plant is concerned, all that is required is a good acetylene generator, purifier, and holder from which the acetylene can be drawn or forced through a meter into a larger storage holder, the meter being connected by gearing with another meter on the pipe leading from the oil-gas holder to the common holder, so that the necessary proportions of the two gases shall be introduced into the common holder simultaneously. From this final holder the enriched gas will be pumped into the cylinders or into a storage cylinder, by means of a thoroughly cooled pump, so that the heat set free by the compression may be safely dissipated.
Whenever still better light is required in railway carriages, as also for the illumination of large, constantly used vehicles, such as omnibuses, the acetone process (cf. Chapter XI.) exhibits notable advantages. The light so obtained is the light of neat acetylene, but the gas is acetylene having an upper limit of explosibility much lower than usual because of the vapour of acetone in it. In all other respects the presence of the acetone will be unnoticeable, for it is a fairly pure organic chemical body, which burns in the flame completely to carbon dioxide and water, exactly as acetylene itself does. If the acetylene is merely compressed into porous matter without acetone, the gas burnt is acetylene simply; but per unit of volume or weight the cylinders will not be capable of developing so much light.
In the United States, at least one railway system (The Great Northern) has a number of its passenger coaches lighted by means of plain acetylene carried in a state of compression in cylinders without porous matter. The gas is generated, filtered from dust, and stored in an ordinary rising holder at a factory alongside the line; being drawn from this holder through a drier to extract moisture, and through a safety device, by a pump which, in three stages, compresses the acetylene into large storage reservoirs. The safety device consists of a heavy steel cylinder filled with some porous substance which, like the similar material of the acetone cylinders, prevents any danger of the acetylene contained in the water-sealed holder being implicated in an explosion starting backwards from the compression, by extinguishing any spark which might be produced there. The plant on the trains comprises a suitable number of cylinders, filled by contact with the large stores of gas to a pressure of 10 atmospheres, pipes of fusible metal communicating with the lamps, and ordinary half-foot acetylene burners. The cylinders are provided with fusible plugs, so that, in the event of a fire, they and the service- pipes would melt, allowing the gas to escape freely and burn in the air, instead of exploding or dissociating explosively within the cylinders should the latter be heated by any burning woodwork or the like. It is stated that this plan of using acetylene enables a quantity of gas to be carried under each coach which is sufficient for a run of from 53 to 70 hours' duration, or of over 3600 miles; that is to say, enables the train, in the conditions obtaining on the line in question, to make a complete "round trip" without exhaustion of its store of artificial light. The system has been in operation for some years, and appears to have been so carefully managed that no accident has arisen; but it is clear that elements of danger are present which are eliminated when the cylinders are loaded with porous matter and acetone. The use of a similar system of compressed acetylene train lighting in South America has been attended with a disastrous explosion, involving loss of life.
It may safely be said that the acetone system, or less conveniently perhaps the mere compression into porous matter, is the best to adopt for the table-lamp which is to be used in occupied rooms Small cylinders of such shapes as to form an elegant base for a table-lamp on more or less conventional lines would be easy to make. They would be perfectly safe to handle. If accidentally or wilfully upset, no harm would arise. By deliberate ill-treatment they might be burst, or the gas-pipe fractured below the reducing valve, so that gas would escape under pressure for a time; but short of this they would be as devoid of extra clangor in times of fire as the candle or the coal-gas burner. Moreover, they would only contaminate the air with carbon dioxide and water vapour, for the gas is purified before compression; and modern investigations have conclusively demonstrated that the ill effects produced in the air of an imperfectly ventilated room by the extravagant consumption of coal-gas depend on the accumulation of the combustion products of the sulphur in the gas rather than upon the carbon dioxide set free.
One particular application of the portable acetylene apparatus is of special interest. As calcium carbide evolves an inflammable gas when it merely comes into contact with water, it becomes possible to throw into the sea or river, by hand or by ejection from a mortar, a species of bomb or portable generator which is capable of emitting a powerful beam of light if only facilities are present for inflaming the acetylene generated; and it is quite easy so to arrange the interior of such apparatus that they can be kept ready for instant use for long periods of time without sensible deterioration, and that they can be recharged after employment. Three methods of firing the gas have been proposed. In one the shock or contact with the water brings a small electric battery into play which produces a spark between two terminals projecting across the burner orifice; in the second, a cap at the head of the generator contains a small quantity of metallic potassium, which decomposes water with such energy that the hydrogen liberated catches fire; and in the third a similar cap is filled with the necessary quantity of calcium phosphide, or the "carbophosphide of calcium" mentioned in Chapter XI., which yields a flame by the immediate ignition of the liquid phosphine produced on the attack of water. During the two or three seconds consumed in the production of the spark or pilot flame, the water is penetrating the main charge of calcium carbide in the interior of the apparatus, until the whole is ready to give a bright light for a time limited only by the capacity of the generator. It is obvious that such apparatus may be of much service at sea: they may be thrown overboard to illuminate separate lifebuoys in case of accident, or be attached to the lifebuoys they are required to illuminate, or be used as lifebuoys themselves if fitted with suitable chains or ropes; they may be shot ahead to illuminate a difficult channel, or to render an enemy visible in time of war. Several such apparatus have already been constructed and severely tested; they appear to give every satisfaction. They are, of course, so weighted that the burner floats vertically, while buoyancy is obtained partly by the gas evolved, and partly by a hollow portion of the structure containing air. Cartridges of carbide and caps yielding a self- inflammable gas can be carried on board ship, by means of which the torches or lifebuoys may be renewed after service in a few minutes' time.
Labels:
acetylene,
Acetylene Production and Power
sundry uses for acetylene
SUNDRY USES
There are sundry uses for acetylene, and to some extent for carbide, which are not included in what has been said in previous chapters of this book; and to them a few words may be devoted.
In orchards and market gardens enormous damage is frequently done to the crops by the ravages of caterpillars of numerous species. These caterpillars cannot be caught by hand, and hitherto it has proved exceedingly difficult to cope with them. However, when they have changed into the perfect state, the corresponding butterflies and moths, like most other winged insects, are strongly attracted by a bright light. As acetylene can easily be burnt in a portable apparatus, and as the burners can be supplied with gas at such comparatively high pressure that the flames are capable of withstanding sharp gusts of wind even when not protected by glass, the brilliant light given by acetylene forms an excellent method of destroying the insects before they have had time to lay their eggs. Two methods of using the light have been tried with astonishing success: in one a naked flame is supported within some receptacle, such as a barrel with one end knocked out, the interior of which is painted heavily with treacle; in the other the flame is supported over an open dish filled with some cheap heavy oil (or perhaps treacle would do equally well). In the first case the insects are attracted by the light and are caught by the adhesive surfaces; in the second they are attracted and singed, and then drowned in, or caught by, the liquid. Either a well-made, powerful, vehicular lamp with its bull's- eye (if any) removed could be used for this purpose, or a portable generator of any kind might be connected with the burner through a flexible tube. It is necessary that the lights should be lit just before dusk when the weather is fine and the nights dark, and for some twenty evenings in June or July, exactly at the period of the year when the perfect insects are coming into existence. In some of the vineyards of Beaujolais, in France, where great havoc has been wrought by the pyralid, a set of 10-candle-power lamps were put up during July 1901, at distances of 150 yards apart, using generators containing 6 oz. of carbide, and dishes filled with water and petroleum 18 or 20 inches in diameter. In eighteen nights, some twenty lamps being employed, the total catch of insects was 170,000, or an average of 3200 per lamp per night. At French prices, the cost is reported to have been 8 centimes per night, or 32 centimes per hectare (2.5 acres). In Germany, where school children are occasionally paid for destroying noxious moths, two acetylene lamps burning for twelve evenings succeeded in catching twice as many insects as the whole juvenile population of a village during August 1902. A similar process has been recommended for the destruction of the malarial mosquito, and should prove of great service to mankind in infected districts. The superiority of acetylene in respect of brilliancy and portability will at once suggest its employment as the illuminant in the "light" moth-traps which entomologists use for entrapping moths. In these traps, the insects, attracted by the light, flutter down panes of glass, so inclined that ultimate escape is improbable; while they are protected from injury through contact with the flame by moans of an intervening sheet of glass.
Methods of spraying with carbide dust have been found useful in treating mildew in vines; while a process of burying small quantities of carbide at the roots has proved highly efficacious in exterminating phylloxera in the French and Spanish vineyards. It was originally believed that the impurities of the slowly formed acetylene, the phosphine in particular, acted as toxic agents upon the phylloxera; and therefore carbide containing an extra amount of decomposable phosphides was specially manufactured for the vine-growers. But more recently it has been argued, with some show of reason, that the acetylene itself plays a part in the process, the effects produced being said to be too great to be ascribed wholly to the phosphine. It is well known that many hydrocarbon vapours, such as the vapour of benzene or of naphthalene, have a highly toxic action on low organisms, and the destructive effect of acetylene on phylloxera may be akin to this action.
As gaseous acetylene will bear a certain amount of pressure in safety—a pressure falling somewhat short of one effective atmosphere—and as pressure naturally rises in a generating apparatus where calcium carbide reacts with water, it becomes possible to use this pressure as a source of energy for several purposes. The pressure of the gas may, in fact, be employed either to force a stream of liquid through a pipe, or to propel certain mechanism. An apparatus has been constructed in France on the lines of some portable fire-extinguishing appliances in which the pressure set up by the evolution of acetylene in a closed space produces a spray of water charged with lime and gas under the pressure obtaining; the liquid being thrown over growing vines or other plants in order to destroy parasitic and other forms of life. The apparatus consists of a metal cylinder fitted with straps so that it can be carried by man or beast. At one end it has an attachment for a flexible pipe, at the other end a perforated basket for carbide introduced and withdrawn through a "man-hole" that can be tightly closed. The cylinder is filled with water to a point just below the bottom of the basket when the basket is uppermost; the carbide charge is then inserted, and the cover fastened down. As long as the cylinder is carried in the same position, no reaction between the carbide and the water occurs, and consequently no pressure arises; but on inverting the vessel, the carbide is wetted, and acetylene is liberated in the interior. On opening the cock on the outlet pipe, a stream of liquid issues and may be directed as required. By charging the cylinder in the first place with a solution of copper sulphate, the liquid ejected becomes a solution and suspension of copper and calcium salts and hydroxides, resembling "Bordeaux mixture," and may be employed as such. In addition, it is saturated with acetylene which adds to its value as a germicide.
The effective gas pressure set up in a closed generator has also been employed in Italy to drive a gas-turbine, and so to produce motion. The plant has been designed for use in lighthouses where acetylene is burnt, and where a revolving or flashing light is required. The gas outlet from a suitably arranged generator communicates with the inlet of a gas- turbine, and the outlet of the turbine is connected to a pipe leading to the acetylene burners. The motion of the turbine is employed to rotate screens, coloured glasses, or any desired optical arrangements round the flames; or, in other situations, periodically to open and close a cock on the gas-main leading to the burners. In the latter case, a pilot flame fed separately is always alight, and serves to ignite the gas issuing from the main burners when the cock is opened.
Another use for acetylene, which is only dependent upon a suitably lowered price for carbide to become of some importance, consists in the preparation of a black pigment to replace ordinary lampblack. One method for this purpose has been elaborated by Hubou. Acetylene is prepared from carbide smalls or good carbide, according to price, and the gas is pumped into small steel cylinders to a pressure of 2 atmospheres. An electric spark is then passed, and the gas, standing at its limit of safety, immediately dissociates, yielding a quantitative amount of hydrogen and free carbon. The hydrogen is drawn off, collected in holders, and used for any convenient purpose; the carbon is withdrawn from the vessel, and is ready for sale. At present the pigment is much too expensive, at least in British conditions, to be available in the manufacture of black paint; but its price would justify its employment in the preparation of the best grades of printers' ink. One of the authors has examined an average sample and has found it fully equal in every way to blacks, such as those termed "spirit blacks," which fetch a price considerably above their real value. It has a pure black cast of tint, is free from greasy matter, and can therefore easily be ground into water, or into linseed oil without interfering with the drying properties of the latter. Acetylene black has also been tried in calico printing, and has given far better results in tone and strength than other blacks per unit weight of pigment. It may be added that the actual yield of pigment from creosote oils, the commonest raw material for the preparation of lampblack ("vegetable black"), seldom exceeds 20 or 25 per cent., although the oil itself contains some 80 per cent, of carbon. The yield from acetylene is clearly about 90 per cent., or from calcium carbide nearly 37.5 per cent, of the original weight.
An objection urged against the Hubou process is that only small quantities of the gas can be treated with the spark at one time; if the cylinders are too large, it is stated, tarry by-products are formed. A second method of preparing lampblack (or graphite) from acetylene is that devised by Frank, and depends on utilising the reactions between carbon monoxide or dioxide and acetylene or calcium carbide, which have already been sketched in Chapter VI. When acetylene is employed, the yield is pure carbon, for the only by-product is water vapour; but if the carbide process is adopted, the carbon remains mixed with calcium oxide. Possibly such a material as Frank's carbide process would give, viz., 36 parts by weight of carbon mixed with 56 parts of quicklime or 60 parts of carbon mixed with 112 parts of quicklime, might answer the purpose of a pigment in some black paints where the amount of ash left on ignition is not subject to specification. Naturally, however, the lime might be washed away from the carbon by treatment with hydrochloric acid; but the cost of such a purifying operation would probably render the residual pigment too expensive to be of much service except (conceivably) in the manufacture of certain grades of printers' ink, for which purpose it might compete with the carbon obtainable by the Hubou process already referred to.
Acetylene tetrachloride, or tetrachlorethane, C_2H_2Cl_4, is now produced for sale as a solvent for chlorine, sulphur, phosphorus, and organic substances such as fats. It may be obtained by the direct combination of acetylene and chlorine as explained in Chapter VI., but the liability of the reaction to take place with explosive violence would preclude the direct application of it on a commercial scale. Processes free from such risk have now, however, been devised for the production of tetrachlorethane. One patented by the Salzbergwerk Neu-Stassfurt consists in passing acetylene into a mixture of finely divided iron and chloride of sulphur. The iron acts as a catalytic. The liquid is kept cool, and as soon as the acetylene passes through unabsorbed, its introduction is stopped and chlorine is passed in. Acetylene and chlorine are then passed in alternately until the liquid finally is saturated with acetylene. The tetrachlorethane, boiling at 147° C., is then distilled off, and the residual sulphur is reconverted to the chloride for use again in the process. A similar process in which the chlorine is used in excess is applicable also to the production of hexachlorethane.
Dependent upon price, again, are several uses for calcium carbide as a metallurgical or reducing reagent; but as those are uses for carbide only as distinguished from acetylene, they do not fall within the purview of the present book.
When discussing, in Chapter III., methods for disposing of the lime sludge coming from an acetylene generator, it was stated that on occasion a use could be found for this material. If the carbide has been entirely decomposed in an apparatus free from overheating, the waste lime is recovered as a solid mass or as a cream of lime practically pure white in colour. Sometimes, however, as explained in Chapter II., the lime sludge is of a bluish grey tint, even in cases where the carbide decomposed was of good quality and there was no overheating in the generator. Such discoloration is of little moment for most of the uses to which the sludge may be put. The residue withdrawn from a carbide-to-water generator is usually quite fluid; but when allowed to rest in a suitable pit or tank, it settles down to a semi-solid or pasty mass which contains on a rough average 47 per cent. of water and 53 per cent. of solid matter, the amount of lime present, calculated as calcium oxide, being about 40 per cent. Since 64 parts by weight of pure calcium carbide yield 74 parts of dry calcium hydroxide, it may be said that 1 part of ordinary commercial carbide should yield approximately 1.1 parts of dry residue, or 2.1 parts of a sludge containing 47 per cent. of moisture; and sludge of this character has been stated by Vogel to weigh about 22.5 cwt. per cubic yard.
Experience has shown that those pasty carbide residues can be employed very satisfactorily, and to the best advantage from the maker's point of view, by builders and decorators for the preparation of ordinary mortar or lime-wash. The mortar made from acetylene lime has been found equal in strength and other properties to mortar compounded from fresh slaked lime; while the distemper prepared by diluting the sludge has been used most successfully in all places where a lime-wash is required, e.g., on fruit-trees, on cattle-pens, farm-buildings, factories, and the "offices" of a residence. Many of the village installations abroad sell their sludge to builders for the above-mentioned purposes at such a price that their revenue accounts are materially benefited by the additional income. The sludge is also found serviceable for softening the feed-water of steam boilers by the common liming process; although it has been stated that the material contains certain impurities—notably "fatty matter"—which becomes hydrolysed by the steam, yielding fatty acids that act corrosively upon the boiler-plates. This assertion would appear to require substantiation, but a patent has been taken out for a process of drying the sludge at a temperature of 150° to 200° C. in order to remove the harmful matter by the action of the steam evolved. So purified, it is claimed, the lime becomes fit for treating any hard potable or boiler- feed water. It is very doubtful, however, whether the intrinsic value of acetylene lime is such in comparison with the price of fresh lime that, with whatever object in view, it would bear the cost of any method of artificial drying if obtained from the generators in a pasty state.
When, on the other hand, the residue is naturally dry, or nearly so, it is exactly equal to an equivalent quantity of quick or slaked lime as a dressing for soil. In this last connexion, however, it must be remembered that only certain soils are improved by an addition of lime in any shape, and therefore carbide residues must not be used blindly; but if analysis indicates that a particular plot of ground would derive benefit from an application of lime, acetylene lime is precisely as good as any other description. Naturally a residue containing unspent carbide, or contaminated with tarry matter, is essentially valueless (except as mentioned below); while it must not be forgotten that a solid residue if it is exposed to air, or a pasty residue if not kept under water, will lose many of its useful properties, because it will be partially converted into calcium carbonate or chalk.
Nevertheless, in some respects, the residue from a good acetylene generator is a more valuable material, agriculturally speaking, than pure lime. It contains a certain amount of sulphur, &c., and it therefore somewhat resembles the spent or gas lime of the coal-gas industry. This sulphur, together, no doubt, with the traces of acetylene clinging to it, renders the residue a valuable material for killing the worms and vermin which tend to infest heavily manured and under-cultivated soil. Acetylene lime has been found efficacious in exterminating the "finger-and-toe" of carrots, the "peach-curl" of peach-trees, and in preventing cabbages from being "clubbed." It may be applied to the ground alone, or after admixture with some soil or stable manure. The residue may also be employed, either alone or mixed with some agglomerate, in the construction of garden paths and the like.
If the residues are suitably diluted with water and boiled with (say) twice their original weight of flowers of sulphur, the product consists of a mixture of various compounds of calcium and sulphur, or calcium sulphides—which remain partly in solution and partly in the solid state. This material, used either as a liquid spray or as a moist dressing, has been said to prove a useful garden insecticide and weed-killer.
There are also numerous applications of the acetylene light, each of much value, but involving no new principle which need be noticed. The light is so actinic, or rich in rays acting upon silver salts, that it is peculiarly useful to the photographer, either for portraiture or for his various positive printing operations. Acetylene is very convenient for optical lantern work on the small scale, or where the oxy-hydrogen or oxy-coal-gas light cannot be used. Its intensity and small size make its self-luminous flame preferable on optical grounds to the oil-lamp or the coal-gas mantle; but the illuminating surface is nevertheless too large to give the best results behind such condensers as have been carefully worked to suit a source of light scarcely exceeding the dimensions of a point. For lantern displays on very large screens, or for the projection of a powerful beam of light to great distances in one direction (as in night signalling, &c.), the acetylene blowpipe fed with pure oxygen, or with air containing more than its normal proportion of oxygen, which is discussed in Chapter IX., is specially valuable, more particularly if the ordinary cylinder of lime is replaced by one of magnesia, zirconia, or other highly refractory oxide.
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acetylene,
Acetylene Production and Power
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